The first thing you do is to create a library where you can store your designs. Every library should be associated with a technology file (from the foundry).
In the CIW window, clicks on File->New->Library. You will see the following window. Fill out library name and path section, and choose technology library, as shown in figure below.
Now, you should see ee103 as one of the libraries in the left most column in the library Manager Window.